METHASOL

2021 - 2024

METHASOL

Produire du méthanol par un procédé durable et rentable basé sur la réduction sélective du CO₂ en phase gazeuse activée par la lumière visible.

Description

Power supply and carbon-intensive industries (cement, steel, limestone, petrochemical and chemical plants and waste incinerator) account for a large share of CO2 emissions. Carbon capture utilisation and storage (CCUS) is one of the only technology solutions that can significantly reduce emissions from these key industrial processes (all of which will remain vital building blocks of modern society) as well as in coal and gas power generation and deliver the deep emissions reductions needed across. Several technologies at different levels of maturity and performances exist for the capture of carbon dioxide, e.g. oxy-fuel combustion, chilled ammonia technology, adsorptive processes, calcium looping, etc.

 

From this capture step, the conversion of CO2 to useful chemicals and fuels is a promising strategy to close the anthropogenic carbon cycle and thereby to reduce CO2 emissions. Various processes exist, depending on the targeted chemical or fuel, they all are quite demanding either in terms of materials used, in case the catalysts are removed and changed regularly, or of energy consumed, for operating the electro-catalysis of the chemical process. Therefore, there is a huge interest in looking into decarbonised and sustainable ways to make CO2 a utilisable material for useful fuels, and artificial photosynthesis is one of them. Obtaining a chemical with high industrial uses but currently mostly produced from fossil fuels transformation, such as methanol, is a way to cut both the carbon emissions of the abovementioned carbon-intensive industries as well as the emissions due to the usual production of the chemical.

 

METHASOL has the ambition to make CCUS a reality for a more sustainable future.

Publications
  1. Amarajothi Dhakshinamoorthy, Sergio Navalón, Ana Primo, Hermenegildo García. 2024. "Selective Gas‐Phase Hydrogenation of CO2 to Methanol Catalysed by Metal‐Organic Frameworks". Angewandte Chemie 136(3): e202311241. DOI .
  2. Celia M. Rueda-Navarro, Zahraa Abou Khalil, Arianna Melillo, Belén Ferrer, Raúl Montero, Asier Longarte, et al.. 2024. "Solar Gas-Phase CO 2 Hydrogenation by Multifunctional UiO-66 Photocatalysts". ACS Catalysis 14(9): 6470-6487. DOI HAL .
  3. Shanping Liu, Valentin Diez-Cabanes, Dong Fan, Lu Peng, Yuanxing Fang, Markus Antonietti, et al.. 2024. "Tailoring Metal-Ion-Doped Carbon Nitrides for Photocatalytic Oxygen Evolution Reaction". ACS Catalysis 14(4): 2562-2571. DOI HAL .
  4. Khaled Dassouki, Sanchari Dasgupta, Eddy Dumas, Nathalie Steunou. 2023. "Interfacing metal organic frameworks with polymers or carbon-based materials: from simple to hierarchical porous and nanostructured composites". Chemical Science 14(45): 12898-12925. DOI HAL .
  5. Sergio Navalón, Amarajothi Dhakshinamoorthy, Mercedes Álvaro, Belén Ferrer, Hermenegildo García. 2023. "Metal–Organic Frameworks as Photocatalysts for Solar-Driven Overall Water Splitting". Chemical Reviews 123(1): 445-490. DOI .
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