Contactez-nous! +33 (0)2 31 45 28 21
lcs@ensicaen.fr
  • Français
Laboratoire Catalyse et SpectrochimieLaboratoire Catalyse et SpectrochimieLaboratoire Catalyse et SpectrochimieLaboratoire Catalyse et Spectrochimie
  • Who are we?
  • Research at LCS
    • Publications
    • EDRF Projects
    • ANR projects
    • Research at LCS
      • Spectrocat group
      • Zeolithes group
    • News
    • Lab activities and organization
    • Education
    • The doctoral and postdocs blog
    • History
  • Technical platforms
    • Catalytic Tests & Chemisorption Platform
    • VISIO platform
    • Solid State NMR platform
      (NMR center of Caen-Normandy)
    • Synthesis & Characterization Platform
  • Industrial partnership
  • Contact us!
    • Work at the lab
    • Contact us!
    • Laboratory staffs
    • LCSValoris serving companies
Next Previous

[CLOSED] Spectroscopy for the speciation and determination of adsorption thermodynamics and surface reaction kinetics of adsorbed species.

28 January 2016

[warning]This position is now closed[/warning]

PhD proposal – LCS – ENSICAEN – University of Caen Normandy, France

project

IR spectroscopy is widely used for characterization of heterogeneous surfaces by adsorption of probe molecules or the elucidation of surface reaction mechanisms. While many information can be used by qualitative analysis of the IR spectra, their use for quantitative purposes is often challenging.

 

We have recently developed methodologies aiming at quantitatively characterizing the chemisorption (number of sites and adsorption thermodynamics) and/or surface reactivity (rate constants and activation energies of surface reactions) using distinct strategies: (i) inversion of spectral data, which allow assessing the distribution of adsorption sites and/or reactivity of surface centers but requires a highly constrained model, and (ii) multivariate curve resolution, that allows more flexibility (from soft to hard-soft constraints), but is mostly efficient for a limited number of distinct species.

 

The present work will aim at combining and implementing both approaches in order to build a versatile toolbox allowing easier and more efficient processing of spectral data obtained on surfaces of catalysts or adsorbants. In particular, these methods will be applied to the characterization of solid acids used for biomass valorization. In particular, they will be extended to the characterization of highly hydrated surfaces or in the liquid phase.

 

Candidate profile

 

The candidate should hold a Master’s degree or equivalent and must have bases in physical chemistry and scientific programming. He (She) will make intensive use of characterization techniques (IR spectroscopy) and chemometrics. Specific skills in these areas would be a plus.

 

Localization: The work will be carried out in the LCS, Caen, France (www-lcs.ensicaen.fr)

 

Starting date : september / October 2016

 

Salary: Grant from the French Ministery of Research, 1700 € gross/month, (~ 1300 € net/month with social benefits and health coverage)

 

Contact :

CV (including contact details of scientific referees) and motivation letter should be sent to :

Arnaud Travert – arnaud.travert@ensicaen.fr  – Tel. +33(0)2 31 45 28 23.

Copyright 2021 - Laboratoire Catalyse & Spectrochimie - Directeur de publication : Guillaume CLET | Creative Commons 4.0 International
  • Français
Laboratoire Catalyse et Spectrochimie
Login

Lost your password?

Reset Password

Log in