Van GESTEL Jacobus
Membre honorifique Associate professor
Enseignant, il ouvrit les yeux d’élèves-ingénieurs et d’étudiants de maîtrise sur les mystères de la catalyse. Après ses études aux Pays-bas, il déroula sa thèse au LCS sous la direction de Duchet, le début d’un compagnonage fructueux.
Spécialiste de l’analyse cinétique, il sut proposer le processus catalytique après modélisation des résultats obtenus lors d’une série minutieuse de réactions sous haute pression, tant en hydrodésulfurisation qu’en isomérisation des alcanes.
Il mêla fréquemment catalyse et étude IR du catalyseur.
Il fut la terreur des gardiens de nuit qu’il blousait en pleine nuit pour venir changer ses réglages de réacteur.
Etude cinetique des reactions d'hydrotraitement : influence du sulfure d'hydrogene et du mode de sulfuration des catalyseurs industriels
Chimie · 1994 · Jacobus Van Gestel
soutenu le 01/01/1994
Les fonctionnalites d'hydrogenation et rupture de liaison carbone-heteroatome de catalyseurs industriels d'hydrotraitement sulfures de cobalt molybdene et nickel molybdene ont ete examinees en etudiant la cinetique de l'influence de l'addition d'hydrogene sulfure sur les vitesses de reaction de composes modeles d'hydrodesazotation (2,6-dimethylaniline), d'hydrodesulfuration (thiophene), et d'hydrogenation (cyclohexene). L'ensemble des resultats est modelise en considerant que pour chaque reaction, l'etape determinante est l'attaque des reactifs par des especes electrophiles protons (hydrogenation) et nucleophiles hydrures et sulfhydryles (rupture de liaison carbone-heteroatome). La vitesse de chaque etape determinante est decrite par une expression unique qui traduit l'intervention des esp… voir plus
DirectionJ. Duchet
Publications
48 publications
1991–2020 1190 citations 16 revues
Aucune publication ne correspond aux filtres.
Jacob Van Gestel, J. Léglise, J. C. Duchet
(2020).
Effect of H2S on the Functionalities of a Co/Mo/A12O3 Hydrotreating Catalyst
, p. 357-372
.
DOI 10.1201/9781003067306-19
book-chapter
Wenbin Chen, Hong Nie, Dadong Li, Xiangyun Long, Jacob Van Gestel, Francoise Maugé
(2016).
Effect of Mg addition on the structure and performance of sulfide Mo/Al2O3 in HDS and HDN reaction
. Journal of Catalysis
, vol. 344, p. 420-433
.
Wenbin Chen, Françoise Mauge, Jacob Van Gestel, Hong Nie, Dadong Li, Xiangyun Long
(2013).
Effect of modification of the alumina acidity on the properties of supported Mo and CoMo sulfide catalysts
. Journal of Catalysis
, vol. 304, n° DOI: 10.1016/j.jcat.2013.03.004, p. 47-62
.
128 citations
DOI 10.1016/j.jcat.2013.03.004
J. Leglise, Jacob Van Gestel, J. C. Duchet
(2010).
ChemInform Abstract: Alkyl Polysulfides as Presulfiding Agents of a CoMo/Al2O3 Catalyst: Effect on Catalytic Properties
. ChemInform
, vol. 24, n° 27, p. no-no
.
M. A Lelias, E. Le Guludec, Laurence Mariey, Jacob Van Gestel, Arnaud Travert, Laetitia Oliviero, et al.
(2010).
Effect of EDTA addition on the structure and activity of the active phase of cobalt-molybdenum sulfide hydrotreatment catalysts
. Catalysis Today
, vol. 150, n° 3-4, p. 179-185
.
Laetitia Oliviero, Laurence Mariey, Marc Antoine Lelias, Sebastien Aiello, Jacob Van Gestel, Françoise Mauge
(2010).
Effect of High Pressure Sulfidation on the Structure of Sulfide Sites of Hydrotreatment Catalysts
. Catalysis Letters
, vol. 135, n° 1-2, p. 62-67
.
Sebastien Lecarpentier, Jacob Van Gestel, Karine Thomas, Jean-Pierre Gilson, Marwan Houalla
(2010).
Influence of W loading on the environment of Si in WO3/ZrO2-SiO2 catalysts
. APPLIED CATALYSIS A-GENERAL
, vol. 374, n° 1-2, p. 137-141
.
8 citations
DOI 10.1016/j.apcata.2009.11.041
Sebastien Lecarpentier, Jacob Van Gestel, Karine Thomas, Jean-Pierre Gilson, Marwan Houalla
(2010).
Influence of W loading on the environment of Si in WO3/ZrO2-SiO2 catalysts
. HAL (Le Centre pour la Communication Scientifique Directe)
.
Jie-Won Park, Karine Thomas, Jacob Van Gestel, Jean-Pierre Gilson, Christine Collet, Jean-Pierre Dath, et al.
(2010).
Study of Ir/WO3/Al2O3 ring opening catalysts
. HAL (Le Centre pour la Communication Scientifique Directe)
.
Jie-Won Park, Karine Thomas, Jacob Van Gestel, Jean-Pierre Gilson, Christine Collet, Jean-Pierre Dath, et al.
(2010).
Study of Ir/WO3/Al2O3 ring opening catalysts
. APPLIED CATALYSIS A-GENERAL
, vol. 388, n° 1-2, p. 37-44
.
20 citations
DOI 10.1016/j.apcata.2010.08.023
M. A Lelias, P. J Kooyman, Laurence Mariey, Laetitia Oliviero, Arnaud Travert, Jacob Van Gestel, et al.
(2009).
Effect of NTA addition on the structure and activity of the active phase of cobalt-molybdenum sulfide hydrotreating catalysts
. Journal of Catalysis
, vol. 267, n° 1, p. 14-23
.
M. A. Lélias, Jacob Van Gestel, F. Maugé, J. A. R. van Veen
(2008).
Effect of NTA addition on the formation, structure and activity of the active phase of cobalt–molybdenum sulfide hydrotreating catalysts
. Catalysis Today
, vol. 130, n° 1, p. 109-116
.
47 citations
DOI 10.1016/j.cattod.2007.07.018
Sebastien Lecarpentier, Jacob Van Gestel, Karine Thomas, Marwan Houalla
(2007).
Study of Ir/WO3/ZrO2–SiO2 ring opening catalysts: Part I: Characterization
. Journal of Catalysis
, vol. 245, n° 1, p. 45-54
.
23 citations
DOI 10.1016/j.jcat.2006.09.018
Christophe Dujardin, Marc-Antoine Lélias, Jacob Van Gestel, Arnaud Travert, Jean-Claude Duchet, Françoise Maugé
(2007).
Towards the characterization of active phase of (Co)Mo sulfide catalyst under reaction conditions – Parallel between IR spectroscopy, HDS and HDN tests
. APPLIED CATALYSIS A-GENERAL
, vol. 322, p. 46-57
.
Sébastien LECARPENTIER, Jacob Van Gestel, Jean-Pierre Dath, Christine Collet, Jean-Pierre Gilson
(2007).
Utilisation d'un catalyseur d'ouverture de cycles hydrocarbones
, n° WO2007006924A1
.
patent
Assignee Total France, Centre National De La Recherche Scientifique
Patent WO2007006924A1
Marc-Antoine Lélias, Christophe Dujardin, Sébastien Aiello, Jacob Van Gestel, Françoise Maugé
(2006).
A comprehensive study of the high-pressure sulfidation effect on the active sites of CoMo(P)/Al2O3 sulfide catalysts
.
conference-paper
Marc-Antoine Lélias, Arnaud Travert, Jacob Van Gestel, Françoise Maugé
(2006).
Comment on “Density Functional Theory Study of Triangular Molybdenum Sulfide Nanocluster and CO Adsorption on It”
. Journal of Physical Chemistry B
, vol. 110, n° 28, p. 14001-14003
.
Angela S. Rocha, Arnaldo C. Faro, Laetitia Oliviero, Marc Antoine Lélias, Arnaud Travert, Jacob Van Gestel, et al.
(2006).
Effect of the electronic properties of Mo sulfide phase on the hydrotreating activity of catalysts supported on Al2O3, Nb2O5 and Nb2O5/Al2O3
. Catalysis Letters
, vol. 111, n° 1-2, p. 27-34
.
Françoise Maugé, Marc Antoine Lélias, Jacob Van Gestel, Arnaud Travert
(2006).
Surface site of sulfide (Co)Mo catalysts. Parallel between IR spectroscopy, HDS and HDN activities
. HAL (Le Centre pour la Communication Scientifique Directe)
.
T. N. Vu, Jacob Van Gestel, J. P. Gilson, C. Collet, J. P. Dath, J. C. Duchet
(2005).
Platinum tungstated zirconia isomerization catalysts: Part I. Characterization of acid and metal properties
. Journal of Catalysis
, vol. 231, n° 2, p. 453-467
.
49 citations
DOI 10.1016/j.jcat.2005.01.037
T. N. Vu, Jacob Van Gestel, J. P. Gilson, C. Collet, J. P. Dath, J. C. Duchet
(2005).
Platinum-tungstated zirconia isomerization catalysts: Part II. Effect of platinum and tungsten loading on the mechanism of isomerization of n-hexane: a kinetic study
. Journal of Catalysis
, vol. 231, n° 2, p. 468-479
.
51 citations
DOI 10.1016/j.jcat.2005.02.003
Christophe Dujardin, Valérie Ruaux, Jacob Van Gestel, Arnaud Travert, Jean-Claude Duchet, Françoise Maugé
(2004).
Impacto del tratamiento con hidrogeno sobre los sitios de superficie de un catalizador CoMo sulfurado, estudio por espectroscopía infrarroja
. HAL (Le Centre pour la Communication Scientifique Directe)
.
Christophe Dujardin, V. Ruaux, Jacob Van Gestel, Arnaud Travert, J.C. Duchet, F. Maugé
(2004).
Impacto del tratamiento con hidrogeno sobre los sitios de superficie de un catalizador CoMo sulfurado, estudio por espectroscopía infrarroja.
.
book
Mikhail V. Luzgin, Karine Thomas, Jacob Van Gestel, Jean-Pierre Gilson, Alexander G. Stepanov
(2004).
Propane carbonylation on sulfated zirconia catalyst as studied by 13C MAS NMR and FTIR spectroscopy
. Journal of Catalysis
, vol. 223, n° 2, p. 290-295
.
33 citations
DOI 10.1016/j.jcat.2004.01.034
Jacob Van Gestel, Vu T. Nghiem, D. Guillaume, J. P. Gilson, J. C. Duchet
(2002).
Surface and Subsurface Platinum in Sulfated Zirconia Catalysts: Relation with Toluene Hydrogenation and n-Hexane Isomerization
. Journal of Catalysis
, vol. 212, n° 2, p. 173-181
.
22 citations
DOI 10.1006/jcat.2002.3765
Jacob Van Gestel, Christophe Dujardin, Françoise Maugé, Jean-Claude Duchet
(2001).
Direct aromatic C-N bond cleavage evidenced in the hydrodenitrogenation of 2,6-dimethyl -aniline over cobalt promoted Mo/Al2O3 sulfide catalysts: a reactivity and FTIR study
. Journal of Catalysis
, vol. 202, p. 78-88
.
Jean-Claude Duchet, Denis Guillaume, A. Monnier, Christophe Dujardin, Jean-Pierre Gilson, Jacob Van Gestel, et al.
(2001).
Isomerization of n-hexane over sulfated zirconia: influence of hydrogen and platinum
. Journal of Catalysis
, vol. 198, p. 328-337
.
J. C. Duchet, D. Guillaume, A. Monnier, C. Dujardin, J. P. Gilson, Jacob Van Gestel, et al.
(2001).
Reply to Zoltán Paál, “Hydrogen Effects in n-Hexane Isomerization on Pt/Sulfated Zirconia. A Comment on the Paper by Duchet et al. (J. Catal.198, 328 (2001))”
. Journal of Catalysis
, vol. 203, n° 2, p. 531
.
M. Baalala, T. Becue, J. Leglise, J. M. Manoli, Jacob Van Gestel, J. Lamotte, et al.
(1999).
Catalyseur d'hydrocraquage à base de sulfure de NiMo déposé sur une zéolithe HEMT modifiée
. Journal de Chimie Physique et de Physico-Chimie Biologique
, vol. 96, n° 2, p. 290-302
.
2 citations
DOI 10.1051/jcp:1999137
Nadia El Azarifi, Abdelhak El Ouassouli, Mahjoub Lakhdar, Abdelaziz Ezzamarty, Jacob Van Gestel, Jacques Leglise
(1999).
Catalyst made of NiMo sulfide supported on hydroxyapatite: influence of Al addition on support properties and on the catalytic conversion of dimethyldisulfide
. Phosphorus Research Bulletin
, vol. 10, n° 0, p. 430-435
.
4 citations
DOI 10.3363/prb1992.10.0_430
J. Leglise, L. Finot, Jacob Van Gestel, J. C. Duchet
(1999).
Conversion of model sulfur compounds to characterize hydrodesulfurization CoMo/Al2O3 catalysts
. Studies in Surface Science and Catalysis
, vol. 127, p. 51--65
.
Studies in Surface Science and Catalysis
Jean-Claude Duchet, Denis Guillaume, Agnès Monnier, Jacob Van Gestel, Georges Szabo, Pedro Nascimento, et al.
(1999).
Mechanism for isomerization of n-hexane over sulfated zirconia: role of hydrogen
. Chemical Communications
, n° 18, p. 1819-1820
.
13 citations
DOI 10.1039/a905855i
A Benyamna, C Bennouna, J Leglise, Jacob Van Gestel, M Duyme, J. C. Duchet., et al.
(1998).
Effect of the Association of Co and Ni on the Catalytic Properties of Sulfided CoNiMo/Al2O3.
. Preprints. American Chemical Society. Division of Petroleum Chemistry
, vol. 43, n° 1, p. 39-42
.
J Leglise, Jacob Van Gestel, L Finot, J. C Duchet, J. L Dubois
(1998).
Kinetics of sulfur model molecules competing with H2S as a tool for evaluating the HDS activities of commercial CoMo/Al2O3 catalysts
. Catalysis Today
, vol. 45, n° 1, p. 347-352
.
17 citations
DOI 10.1016/s0920-5861(98)00260-0
W. R. A. M. Robinson, Jacob Van Gestel, T. I. Korányi, S. Eijsbouts, A. M. van der Kraan, J. A. R. van Veen, et al.
(1996).
Phosphorus Promotion of Ni(Co)-Containing Mo-Free Catalysts in Quinoline Hydrodenitrogenation
. Journal of Catalysis
, vol. 161, n° 2, p. 539-550
.
149 citations
DOI 10.1006/jcat.1996.0216
Jacob Van Gestel, L. Finot, J. Leglise, J. C. Duchet
(1995).
CoMo/Al2O3 VERSUS NiMo/Al2O3 SULPHIDE CATALYSTS : SENSITIVITY TO REACTION CONDITIONS FOR HDS AND HYDROGENATION
. Bulletin des Sociétés Chimiques Belges
, vol. 104, n° 4-5, p. 189-195
.
20 citations
DOI 10.1002/bscb.19951040403
Jacob Van Gestel, J. Leglise, J. C. Duchet
(1994).
Catalytic Properties of a Como/Al2O3 Catalyst Presulfided with Alkyl Polysulfides: Comparison with Conventional Sulfiding
. Journal of Catalysis
, vol. 145, n° 2, p. 429-436
.
48 citations
DOI 10.1006/jcat.1994.1053
Jacob Van Gestel, J. Léglise, J. C. Duchet
(1994).
Effect of Hsub 2S on the functionalities of a Co/Mo/Alsub 2Osub 3 hydrotreating catalyst
. OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)
.
Jacob Van Gestel
(1994).
Etude cinetique des reactions d'hydrotraitement : influence du sulfure d'hydrogene et du mode de sulfuration des catalyseurs industriels
.
thesis
J Leglise, Jacob Van Gestel, J-C Duchet
(1994).
Evidence for H2S as Active Species in the Mechanism of Thiophene Hydrodesulphurization.
. Preprints. American Chemical Society. Division of Petroleum Chemistry
, vol. 39, n° 4, p. 533-537
.
S. Eijsbouts, Jacob Van Gestel, E.M. van Oers, R. Prins, J.A.R. van Veen, V.H.J. de Beer
(1994).
In situ poisoning of the thiophene hydrodesulfurization activity of carbon-supported transition metal sulfide catalysts by phosphorus
. APPLIED CATALYSIS A-GENERAL
, vol. 119, n° 2, p. 293-303
.
8 citations
DOI 10.1016/0926-860x(94)85198-0
J. Leglise, Jacob Van Gestel, J. C. Duchet
(1994).
Promotion and inhibition by hydrogen sulfide of thiophene hydrodesulfurisation over a sulfide catalyst
. Journal of the Chemical Society, Chemical Communications
, n° 5, p. 611-612
.
9 citations
DOI 10.1039/c39940000611
J Leglise, Jacob Van Gestel, C Duchet J.
(1993).
Alkyl polysulfides as presulfiding agents of a CoMo/Al2O3 catalyst: Effect on catalytic properties.
. Phosphorus, Sulfur and Silicon and the Related Elements
, vol. 74, n° 1-4, p. 479-480
.
J. Léglise, Jacob Van Gestel, J. C. Duchet
(1993).
Alkyl Polysulfides as Presulfiding Agents of a CoMo/Al2O3Catalyst: Effect on Catalytic Properties
. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
, vol. 74, n° 1-4, p. 479-480
.
1 citation
DOI 10.1080/10426509308038173
Jacob Van Gestel, J. Léglise, J. C. Duchet
(1993).
ChemInform Abstract: Effect of Hydrogen Sulfide on the Reaction of 2,6‐Dimethylaniline over Sulfided Hydrotreating Catalysts.
. ChemInform
, vol. 24, n° 11
.
Janine Szabo, Georges Szabo, Jacob Van Gestel, Daniel Cornet
(1993).
Isomerization of n-butenes to isobutene catalyzed by fluorinated alumina: Reaction kinetics
. APPLIED CATALYSIS A-GENERAL
, vol. 96, n° 2, p. 319-330
.
16 citations
DOI 10.1016/0926-860x(90)80019-b
Jacob Van Gestel, J. Leglise, J. -C. Duchet
(1992).
Effect of hydrogen sulphide on the reaction of 2,6-dimethylaniline over sulphided hydrotreating catalysts
. APPLIED CATALYSIS A-GENERAL
, vol. 92, n° 2, p. 143-154
.
29 citations
DOI 10.1016/0926-860x(92)80312-z
S. Eijsbouts, Jacob Van Gestel, J. A. R. Van Veen, V. H. J. De Beer, R. Prins
(1991).
The effect of phosphate on the hydrodenitrogenation activity and selectivity of alumina-supported sulfided Mo, Ni, and NiMo catalysts
. Journal of Catalysis
, vol. 131, n° 2, p. 412-432
.
135 citations
DOI 10.1016/0021-9517(91)90276-a
